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Thermodynamic derivatives of the canonical partition function
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Canonical partition function
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Canonical differentiation gives
F
=
−
β
−
1
lo
g
Z
,
⟨
E
⟩
=
−
∂
β
lo
g
Z
,
(
Δ
E
)
2
=
∂
β
2
lo
g
Z
.
(35)
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Canonical energy fluctuation
Thermodynamic derivatives of the canonical partition function
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Canonical partition function
Canonical ensemble
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