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For a mixed spin-half state, the Bloch vector formula gives
Physical consistency is equivalent to the resulting Bloch vector having length at most one.
Three linearly independent Hermitian operators do not always suffice. The operators
are linearly independent, but the first expectation is always one and none detects the component. States with Bloch vectors and have identical expectations for all three. The correct criterion for informationally complete three-observable qubit tomography is that the three traceless parts span the Pauli space.
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