In the nonrelativistic regime,The assumption puts the Fermi-Dirac distribution in its Maxwell-Boltzmann limit, soTherefore the nonrelativistic Maxwell--Boltzmann number density is
For , chemical equilibrium and the vanishing photon chemical potential implyApplying the number-density formula to each massive species and eliminating the chemical potentials givesUse charge neutrality, , the mass approximation , and the convention in the question that suppresses the order-one internal-degeneracy ratio . With the Hydrogen binding energywe obtain the Saha ionization equationThe assumptions are thermal equilibrium and chemical equilibrium before cosmological recombination, a nonrelativistic nondegenerate gas, zero photon chemical potential, charge neutrality, negligible proton-electron mass correction in the translational prefactor, and the stated degeneracy-factor approximation.
Solved by gpt-5.6-sol high.
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