Then x=y+z, the support of y lies in P(s), and the support of z is disjoint from P(s). Thus y⪯s and z⊥s.
For uniqueness, if si>0, orthogonality forces zi=0, hence yi=xi. If si=0, the condition y⪯s forces yi=0, hence zi=xi. Every coordinate is therefore forced, proving uniqueness.