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Odd-state variational principle for an even potential
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Area of mathematics
Algebra
Linear algebra
Linear operator theory
Rayleigh quotient
Rayleigh-Ritz variational principle
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Words: 34
For a one-dimensional even potential, the ground state is even and the first excited state is odd. Every normalized odd trial wavefunction is therefore orthogonal to the ground state and gives
E
1
≤
⟨
ψ
odd
,
H
ψ
odd
⟩
.
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Rayleigh-Ritz variational principle
Rayleigh quotient
Linear operator theory
Linear algebra
Algebra
Area of mathematics
Mathematics
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