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Entropic Hooke law for a one-dimensional chain
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One-dimensional freely jointed chain
Fixed-tension partition function of a one-dimensional chain
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The physical tension is
f
=
k
B
T
τ
. At small extension,
f
∼
n
a
2
k
B
T
L
.
(3)
At fixed tension the extension is
L
=
na
tanh
(
f
a
/
(
k
B
T
))
and decreases as temperature rises.
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(6)
Fixed-tension partition function of a one-dimensional chain
One-dimensional freely jointed chain
Statistical physics
Branch of physics
Physics
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