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Chemical-potential balance for a reaction
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For a reaction with stoichiometric changes
ν
i
, varying the reaction extent at fixed temperature and pressure gives
d
G
=
(
∑
i
ν
i
μ
i
)
d
ξ
.
(25)
Equilibrium requires
∑
i
ν
i
μ
i
=
0
.
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Gibbs free energy
Thermodynamics
Statistical physics
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